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The mechanical design of the crystallizer has a significant influence on the nucleation rate due to contact nucleation (that which is caused by contact of the crystals with each other and with the pump impeller or propeller when suspended in a supersaturated solution).
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Each application must be evaluated on an individual basis to achieve optimum results. Therefore, each crystallization plant requires many unique features based upon well-established general principles. While crystallization is a unit operation embracing well known concepts of heat and mass transfer, it is nevertheless strongly influenced by the individual characteristics of each material handled.
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Because the pattern or arrangement of the atoms is repeated in all directions, there are definite limitations on the shapes which crystals may assume.įor each chemical compound, there are unique physical properties differentiating that material from others, so the formation of a crystalline material from its solution, or mother liquor, is accompanied by unique growth and nucleation characteristics. Crystals are, in short, high-purity products with consistent shape and size, good appearance, high bulk density, and good handling characteristics. The inter-atomic distances in a crystal of any definite material are constant and characteristic of that material. A crystal may be defined as a solid composed of atoms arranged in an orderly, repetitive array. Crystallization is the process by which a chemical is separated from solution as a high-purity, definitively shaped solid.